Solution to 1992 Problem 58


Electron orbitals are filled in the order n = 0\ l = 0, n = 1\ l = 0, n = 1\ l = 1, n = 2\ l = 0, n = 2\ l = 1, n = 2\ l = 2, etc until the fourth row of the periodic table (starting with potassium (Z = 19)). Sodium comes before this, so its orbitals are filled by first filling n = 0\ l = 0 (2 electrons), then filling n = 1\ l = 0 (2 more electrons), then filling n = 1\ l = 1 (6 more electrons), then filling the first electron in the n = 2\ l = 0 subshell. This electron configuration can be written as 1\text{s}^2 2\text{s}^2 2\text{p}^6 3\text{s}. Therefore, answer (C) is correct.


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